Contaminant Chemistry Overview
Functional Groups, Chemical Properties, and Hazards
Transport Mechanisms
Advection
Mechanical Dispersion
Diffusion (Chemical Dispersion)
3- and 4-Phase Equilibrium Partitioning
Adsorption and Absorption
Applications of Kd, Koc, foc, Kow, and KH
NAPL and the One Percent Rule
Molar Fraction Calculation
Contaminant Mass Fraction Calculation
Residual Saturation Calculation
Groundwater Transport
Hydrogeology Review
Three Point Problem
Contaminant Velocity Calculations
Nonaqueous Phase Liquid (NAPL) Transport
Capillary Fringe Interactions and Smear Zones
Estimating LNAPL Thickness from Well Free Product
Estimating DNAPL Critical Height
Vapor Transport
Contaminant Vapor Properties and Behavior
Vapor Transport (cont.)
Henry's Law Partitioning
Vapor Diffusion and Air-Filled Porosity
Natural Attenuation
Natural Attenuation Processes
Biodegradation Pathways for Common Contaminants
Focus on Hydrocarbon Contamination
Gasoline and Diesel Chemistry
BTEX, Oxygenates, and Additives
Ethanol Cosolvation and Plume Elongation
Geochemical Indicators of Natural Attenuation
Plume Behavior and Zones
Focus on Chlorinated Hydrocarbon Contamination
Chlorinated Solvent Chemistry
Plume Behavior Classification
Degradation Pathways
Focus on Metal Contaminants
Mobility, pH, and Amphoterism
Dissolved and Particulate Forms
Cation/Anion Exchange and Variably Charged Soils
Complexation, Chelation, and Ligands
Hydrated Metals as Acids
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