Principles of Contaminant Transport and Fate in Soil and Groundwater - A Focus On Petroleum, Chlorinated Solvents, and Metals - California State Water Resources Control Board, Sacramento, CA

  • October 11, 2016
  • 8:00 AM
  • October 12, 2016
  • 5:00 PM
  • Cal EPA, State Water Resources Control Board, 1001 I Street, 2nd floor, Klamath Room, Sacramento, CA 95814

October 11 - 12, 2016, 8 A.M. to 5 P.M. (2 Days)

Cal EPA, State Water Resources Control Board
1001 I Street, 2nd floor, Klamath Room
Sacramento, California 95814


Note: This is a private class for California State Water Resources Control Board and other Cal EPA staff only. Please register internally. Please inquire by email if you would like to schedule a public class in your area.

Instructor: Erick McWayne, NEMA, LLC

Overview: This course provides the practical knowledge and skills necessary to effectively assess, clean up, and manage contaminated sites. The course begins with an overview of chemical partitioning and hydrogeology, and concludes with in-depth coverage of petroleum, chlorinated solvents, and metals contamination.

Course Topics:

Contaminant Chemistry Overview

  • Functional Groups, Chemical Properties, and Hazards

Transport Mechanisms

  • Advection

  • Mechanical Dispersion

  • Diffusion (Chemical Dispersion)

  • Effective Solubility

3- and 4-Phase Equilibrium Partitioning

  • Adsorption and Absorption

  • Applications of Kd, Koc, foc, Kow, and KH

  • NAPL and the One Percent Rule

  • Molar Fraction Calculation

  • Contaminant Mass Fraction Calculation

  • Residual Saturation Calculation

Groundwater Transport

  • Hydrogeology Review

  • Three Point Problem

  • Contaminant Velocity Calculations

Nonaqueous Phase Liquid (NAPL) Transport

  • Capillary Fringe Interactions and Smear Zones

  • Estimating LNAPL Thickness from Well Free Product

  • Estimating DNAPL Critical Height

Vapor Transport

  • Contaminant Vapor Properties and Behavior

  • Henry's Law Partitioning
 

Vapor Transport (cont.)

  • Vapor Diffusion and Air-Filled Porosity

  • Barometric Pumping

Natural Attenuation

  • Natural Attenuation Processes

  • Biodegradation Pathways for Common Contaminants

Focus on Hydrocarbon Contamination

  • Gasoline and Diesel Chemistry

  • BTEX, Oxygenates, and Additives

  • Ethanol Cosolvation and Plume Elongation

  • Geochemical Indicators of Natural Attenuation

  • Plume Behavior and Zones

Focus on Chlorinated Hydrocarbon Contamination

  • Chlorinated Solvent Chemistry

  • Plume Behavior Classification

  • Degradation Pathways

  • Geochemical Indicators of Natural Attenuation

Focus on Metal Contaminants

  • Mobility, pH, and Amphoterism

  • Dissolved and Particulate Forms

  • Cation/Anion Exchange and Variably Charged Soils

  • Complexation, Chelation, and Ligands

  • Hydrated Metals as Acids


Education Level: Introductory to intermediate/refresher.

Course Materials: Course proceedings, worksheets, and reference material.

Registration: Please register via the Cal EPA Water Board Training Academy system.

Credit: 15 PDHs and 1.5 CEUs for completing 15 hours of instruction.

About the Instructor: Erick McWayne has twenty-two years of professional experience in water quality management and teaching related courses. As a consultant, he managed contaminated surface water and groundwater projects for the Department of Defense and other clients. He currently provides consulting support to water quality projects and teaches courses in contaminant chemistry, transport and fate, geochemistry, hydrogeology, remediation, stormwater and surface water management, and contaminant attenuation with both the University of California Davis and the National Environmental Management Academy. Between teaching and consulting, Erick develops surface water and stormwater treatment technologies. He holds two patents on permeable reactive weir technology.

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